Stable carbocation chemistry /
edited by G.K. Surya Prakash and Paul v.R. Schleyer.
- New York : John Wiley, c1997.
- xvi, 587 p. : ill., figs., tables ; 24 cm.
"A Wiley-Interscience publication." "This book developed from a Loker Hydrocarbon Research Institute Symposium on Carbocation Chemistry, held in January 1992 on the occaion of George A. Olah's sixty-fifth birthday"--Pref.
Includes bibliographical references and index.
Foreword / Preface / Recollection of My Search for Stable Long-Lived Carbocations in Superacid Solution / Accurate Carbocation Structures: Verification of Computed Geometries by NMR, IR, and X-Ray Diffraction / Investigation on [mu]-Hydridobridged Carbocations in Superacids: The Effect of Ring Size on Transannular Participation / New Carbocations and Dications / Excursions into Long-Lived Vinyl Cations: NMR Spectroscopic Characterization of [alpha]-Aryl Vinyl Cations / Structure and Dynamics of [actual symbol not reproducible] Ions: An Experimental and Theoretical Comparison / Some Aspects of Carbocation Rearrangements / J. D. Roberts -- G. K. Surya Prakash and Paul von Rague Schleyer -- George A. Olah -- Paul von Rague Schleyer, Christoph Maerker, Peter Buzek and Stefan Sieber -- Ted S. Sorensen -- G. K. Surya Prakash -- Hans-Ullrich Siehl -- Per Ahlberg -- V. G. Shubin and G. I. Borodkin -- 1. 2. 3. 4. 5. 6. 7. Coordination and Electron Transfer to Carbenium Ions: Direct Access to Bond Energies in Solution / Recent Applications of the Isotopic Pertubation Method for Determining the Details of Carbocation Structures / Isotope Effects as a Probe of Subtle Features of Carbocation Structure in Superacids / Infrared Spectroscopy of Long-Lived Carbocations in Cryogenic SbF[subscript 5] Matrices / CPMAS NMR of Carbocations at Cryogenic Temperatures / Surface and Interface Studies of Organic Ions / X-Ray Crystal Structure Analyses of Carbocation Salts and Related Compounds / Industrially Important Electrophilic Functionalization of Alkanes Under Superacid Catalysis / Edward M. Arnett and Robert A. Flowers II -- M. Saunders, H. A. Jimenez-Vazquez and O. Kronja -- David A. Forsyth -- Dionis E. Sunko -- Philip C. Myhre and Costantino S. Yannoni -- D. T. Clark -- Thomas Laube -- Jean Sommer -- 8. 9. 10. 11. 12. 13. 14. 15. Electrophilic Species That Can React with Benzene Are Dicationic / Natural Product Chemistry in Superacids / Koichi Shudo and Tomohiko Ohwada -- Jean-Claude Jacquesy. 16. 17.